After removing three socks
remaining socks =12-3 = 9 socks
The 3 socks removed could be either 3 blacks, 3 whites , 1 black and 2 whites, 2 blacks and 1 white
$$let\ black\ =B\ and\ white\ =W$$
Statement 1
The socks that remain in the drawer have a ratio of 2B to 1W
$$9\ socks\ =\frac{\left(2B+2B+2B\right)}{\left(1W+1W+1W\right)}=\frac{6B}{3W}=6B:2W$$
Hence, there are 6 Blacks remaining in the drawer.
$$Statement\ 1\ is\ INSUFFICIENT$$
Statement 2
One of the first two socks removed is black, This means that from the first two socks removed, at least one of them is Black.
From the question, three socks were removed from the three socks there are two different possibilities;
1B and 2W or 2B and 1W ; this information doesn't tell us about the remaining 9 socks.
Hence Statement 2 is INSUFFICIENT
Statement 1 alone is SUFFICIENT
$$answer\ is\ option\ A$$