Hello Vemuri.
Sorry for late reply, I was quiet busy for the last couple of days
Total number of ways possible = 5! = 120 ways.
The probability that the couples sit together = 24/120 = 1/5
So, the probability that the couples do not sit together = 4/5
Well What have you calculated is the arrangement of chairs and not the people!!
Let [] ==> denotes each chair
Let the couple be denoted by C1 and C2 and the other single person By S
Please draw 6 chairs in some scratch paper for better understanding
[] [] [] [] [] []
Lets first sit C1
[C1] [] [] [] [] []
Now C2 can take only the adjacent seat
[C1] [C2] [] [] [] []
now S can seat in 4 different ways(4 empty chairs!)
Although, C1 and C2 can also be interchanged as C1 C2 or C2 C1 which I will deal latter in this question
Similarly,
for another Seating arrangement like this
[] [C1] [C2] [] [] []
Now again S can be seated in 4 different ways,one on left of C1 and 3 on right of C2
[] [] [C1] [C2] [] []
Again 4 types of seating arrangements for S
Now if we further advance C1 C2 to the right, the Second arrangement again occurs
[] [] [] [C1] [C2] []
So we are not going to count this arrangement.
So at Max, there can be 3 different arrangements(Bold Face) having 4 types of seating arrangement of S
thus, 3*4 = 12
Further, this seating arrangement of C1 C2 Can be interchanged as C2 and C1
12*2 = 24
And Total Number of Arrangements of 3 people in 6 chairs is
6*5*4/2! =120/2 = 60
two people as couples(same type) = 2!
So ways of couple not seating togather is 60-24 =36
So probability = 36/60 =3/5
Hope now everything is clear!!