The thing is, with angles it matters what's in the middle of the three letters. For instance, RSQ has the point at S, while QRS has the point at R. Those are two completely different angles. It's the same with UST and STU: one has the point at S, while the other has the point of the angle at T.
As to why I'm dividing by 2: the triangle QRS is isosceles, since it has two sides that have the same length. This means that angles RQS and RSQ are are equal. In any given triangle, the sum of angles is always 180 degrees, which means that you have the following relationship:
RQS + RSQ + QRS = 180
But the first two are equal, so:
2RSQ + QRS = 180
so in the end:
2RSQ = 180 - QRS
RSQ = (180 - QRS)/2
Hope this helps!