For these types of questions, I would focus on the decimal part since it signifies the remainder.
Now we have decimal part = 0.45 = 45/100; lets reduce it to the simplest fraction form:
45/100 = 9/20. Therefore we know that when one of the INTEGERS "a" is divided by "b"; remainder is a multiple of 9 (the numerator). Now just look for the number which is NOT a multiple of 9. [spoiler](3 is the correct answer).[/spoiler]
Let me know if this helps

















