If x is just on one side of the equation then by definition of modulus
|x| = -x if x is negative
|x| = x if x is positive or 0
For example |X| = 2
Case1: x=2
Case2: -x = 2
x = -2
Since |2| = 2 and | - 2 | = - ( - 2) = 2
By definition this holds good
PART 2
If x is on both sides of the equation
then we have 4 cases +/+,-/-,+/- and -/+
Case 1: +/+
| x – 3 | = | 3x + 2 | – 1
x-3 = 3x+2-1
Case 2: -/-
- (x-3) =
- (3x+2) - 1
Case 3: +/-
x-3 =
- (3x+2) - 1
Case 4: -/+
- (x-3) = 3x+2-1
You could get different values of x but you need to subsitute it back in the equation to see which value of x works i.e satisfies the equation
Hope this helps!
P.S I was just as confused as you in the beginning when I saw absolute value equations; now i feel slighlty better

I learnt PART 2 from one of Ron's(GMAT expert on this site) posts in a different forum.