Consider the following sibling pairs S1, S2, and S3
S1 (A,B) S2(C,D) S3(E,F,G)
Now the probability of selecting A is 1C1. If A is selected then B cannot be selected and every other person can be selected. Thus the pairs can be AB, AC, AD, AE, AF, AG where the order of the selection doesn't matter. So the probability of this selection is 1C1 * 5C1 / 7C2.
In the same way, B can also be paired with 5 other persons but not A.
BC, BD, BE, BF, BG. So the selection probability is 1C1*5C1/7C2.
Now consider the selection of C. CE, CF, CG i.e. 1C1*3C1/7C2 (since CA and CB have already been counted).
Same with D. DE, DF, DG i.e. 1C1*3C1/7C2 (Since DA, DB have already been counted).
However when we select E we cannot select the persons F and G, since they are kins. Also we cannot select any other person from the 4 people since that pair has already been counted above.
Same goes for F and G. Thus the total probability of selection is
5C1/7C2 + 5C1/7C2 + 3C1/7C2 + 3C1/7C2 = 16C1/7C2 = 16/21