My Answer is 2/5
Let the couple be Aa Bb and C( single person )
out of 5 places
Assume if C takes the 1st place
A can take the first place in 4 ways , a cannot take the second place. it has to be taken by wither B or b hence is 2 ways and the last 2 places in 1 way
hence 1*4*2*1*1 = 8 ways
Assume C takes the 5 th place - 8 ways same as above.
Assume C takes the 2 second place its (4*1*2*1*1) = 8 ways
Assume C takes the 4th place - 8 ways same as above
If C takes the 3rd place
1st place in 4 ways , 2nd place in 2 ways , 4th place in 2 place and 5th place in 1 way
hence its 4*2*1*2*1 = 16.
therefore its
8+8+8+8+16 = 48 ways.
5 people can arrange themselves in 5! = 120
thus the probability is 48/120 which is 2/5.
hope it helps..