emiflo wrote:hi guys. pls could someone solve this for me. the rate of a chemical reaction is directly proportional to the square of concentration of chemical A and inversely proportional to the concentration of chemical B. If the concentration of chemical B is increased by 100 percent, which of the following is closest to the percentage change in concentration of chemical A required to keep the reaction unchanged.
A 100% decrease
B 50% decrease
C 40% decrease
D 40% increase
E 50% increase
The problem describes the following relationship:
r =(A^2)/B
Why? Two reasons:
1) The rate is
directly proportional to A^2, and directly proportional means that as one value increases, the other also increases by a proportionate amount. In the equation above, if we double r, we'll have to double the value of A^2 for the equation to remain valid. So the equation represents the directly proportional relationship between r and A^2.
2) The rate is
inversely proportional to B, and inversely proportional means as one value increases, the other
decreases by a proportionate amount. In the equation above, if we double r, we'll have to halve the value of B for the equation to remain valid. (Multiplying the left side by 2 is the same as dividing the right side by 1/2). So the equation represents the inversely proportional represent between r and B.
Now let's plug in values.
Let A = 10 and B = 2.
r = (10^2)/2 = 100/2 = 50.
If we increase B by 100%, new B = 4.
If we want the rate to stay the same, we get:
50 = (A^2)/4
A^2 = 200
New A = Root200 = 10Root2 = 14 approximately
% change in A = Difference/(Original A) * 100 = (14-10)/10 * 100 = 4/10 * 100 = 40%.
The correct answer is D.
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