I'm going to go with D - 2/5. There are 120 ways to arrange the 5 people. Call them A,B,C,D,E and let A,B and C,D be the couples and E be the single. I looked at this by fixing the position of the single person and then evaluating how many arrangments of the others are possible. For example, if E is in the first seat, then you have the following
(E)---(4 choices)---(2 choices)---(1 choice)---(1 choice)
The second seat can clearly be A,B,C,or D, then the 3rd must be a member of the other couple, the fourth must be the parter of the person in the second seat, and the last must be the partner of the 3rd. So 4*2*1*1 = 8 arrangements. If E is in the second seat, you get
(4 choices)---(E)---(2 choices)---(1 choice)---(1 choice)
Note the 3rd seat cannot be occupied by the partner of the first since this would leave the other couple to occupy 4 and 5. Again this yields 8 arrangements. If E is in the middle seat, you get
(4 choices)---(2 choices)---(E)---(2 choices)---(1 choice)
for 16 arrangements. Since putting E in the 4th and 5th seat will be the same as the 1st and 2nd seats, just in reverse order, we know the possible outcomes without a couple sitting together are 8+8+16+8+8 = 48. Since the total number of arrangements is 120, the probability is 48/120 = 2/5.