Symmetry about a point most commonly comes up in coordinate geometry when you're graphing functions. A function is said to be symmetric about the point (0,0) (the origin) if for every point (a,b) that's on the graph, there is a corresponding point (-a,-b) that is also on the graph. This type of function is called an odd function. y=x^3 is an example of an odd function. Note a few sample points: (2,8) AND (-2,-8) are on the graph. (3,27) AND (-3,-27) are on the graph. Also, if we connect any two corresponding points with a line segment, the midpoint of the segment will be the origin. This is essentially how you should think of it having symmetry with respect to the point (0,0). Both corresponding points lie on a line that goes through the origin, and the distance from each point to the origin is the same.
Symmetry about a point on a number line is defined essentially the same way. If two points are symmetric about zero, they should be equidistant from and on opposite sides of zero. So, to answer your first question, yes, the two distances should be equal.
Finally, remember that this is a a data sufficiency question, and the answer being B doesn't mean you can use statement 2 to prove that the two points are symmetric about zero. It just means that you can use statement 2 to provide a definitive yes or no answer to the question of the points' symmetry about zero.
So, just focusing on statement 2: Assume A and B do have symmetry about zero. Let B=x and A=-x. Hopefully it is clear that if there is any hope of statement 2 being true, it must be true that 0<x<1, so let's make this assumption. The distance from 0 to A is |-x|=x. The distance from 1 to B is |1-x|=1-x. We need the sum of these distances to be less than 1, so: x+1-x<1, which simplifies to 1<1. This is false which implies that the points can't be symmetric about zero if statement 2 is true.
So, you're right that the distances are not equal when you take statement 2 to be true which is precisely why it's sufficient. If statement 2 is true, we know for sure the answer to the original question is no.