Hi Winnie here are the details
A preposition is a word governing, and usually coming in front of, a noun or pronoun and expressing a relation to another word or element, as in:
She left before breakfast
What did you come for?
Prepositions generally introduce prepositional phrases. Prepositional phrases look like this:
preposition + optional modifiers + noun, pronoun or gerund
At school
At = preposition; school = noun.
According to us
According to = preposition; us = pronoun.
Some prepositions also function as subordinate conjunctions. These prepositions are after, as, before, since, and until. A subordinate conjunction will have both a subject and a verb following it, forming a subordinate clause.
As Jerome buckled on the parachute
As = subordinate conjunction; Jerome = subject; buckled = verb.
There can be a long long list of prepositions. i cant even write all of them....
Answer to your second question---
all -ing words are not complex. i mean i think you are relating them to verb-ing form.
during is a preposition because its not a verb-ing form. there is no verb there. hence its a preposition
eg- kindly don't sleep during my lectures!
He died during the war.
hence its used as a preposition.
i have tried to make you understand in short. let me know if you need explanation of anything specific here.