Hi Joy Shaha,
You would likely find it easiest to use 'brute force' on this question.
We're told that both A and B are POSITIVE INTEGERS and that 4A + 5B = 27. Since 27 is such a relatively 'small' number and there IS a definitive answer to the given question, there must be just one solution to given equation. We just have to do enough 'brute force' arithmetic to find it....
IF.... A=1, then 5B = 23... that does NOT lead to an integer value for B though, so A=1 is not possible.
IF.... A=2, then 5B = 19... that does NOT lead to an integer value for B though, so A=2 is not possible.
IF.... A=3, then 5B = 15... that DOES lead to an integer value for B (B=3), so A=3, B=3 IS correct.
The question asks for the value of 2A + 3B.... 2(3) + 3(3) = 15
Final Answer: A
GMAT assassins aren't born, they're made,
Rich