Hi 800_or_bust,
Certain questions on Test Day are easier to solve if you 'play around' and do work in 'small pieces.'
In this prompt, you don't have much to work with, but you should notice that the two line segments are both DIAGONALS. Since we're dealing with a cube, those two diagonals would be the SAME length.
From there, you might think...since those two are the SAME length, if I formed a triangle with them, then that triangle would be ISOSCELES. That deduction, in and of itself, isn't that meaningful... BUT it should get you thinking about forming a triangle using those two line segments....
Drawing a quick sketch and including that new line segment across the "top" of the cube will help you to notice that that third line is ALSO a diagonal that has the SAME length as the other two line segments.
NOW you have a triangle with 3 equal sides... THAT is an EQUILATERAL triangle and determining the angle isn't very hard at all at that point.
GMAT assassins aren't born, they're made,
Rich