You don't need to know about decks of cards for the GMAT, but in a standard deck, there are four suits, and 13 cards of each suit. Now to the question: it doesn't matter what card you pick first. After you've picked the first card, there are 51 cards left, 39 of which are of a different suit from the first card. So the probability is 39/51 = 13/17 (as a side note, fractions will always be reduced on the GMAT, so the answer choices are bizarre here).
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