I think it's going to be easier to find the number of ways in which they do sit together, then subtract from 1.
Let's call one couple A1-A2, the other couple B1-B2, and the single person C.
Ways in which both couples sit together:
If we treat each couple as a unit, then we have 3 units to arrange. 3! = 6, but for each couple we have two ways to arrange: A1-A2 & A2-A1, B1-B2 and B2-B1. This means that for each of those 6 arrangements, we can flip the people in couple A or couple B and create a new arrangement. 3! * 2! (ways to arrange A) * 2! (ways to arrange B) = 24.
Ways in which one couple sits together:
Let's use couple A as the one sitting together. We know have 4 units to arrange: A, B1, B2, and C. 4! = 24, but again, we can flip the people in couple A to create a new arrangement. 4! * 2! = 48. HOWEVER, this includes all of the arrangements where B1 and B2 end up sitting together as well. We know that number is 24, so we must subtract it. 48-24 = 24.
We also must remember that couple B could be the couple sitting together. For each of the couple A arrangements, we could swap them with couple B, giving us 24 more arrangements, for a total of 48 arrangements where exactly one couple sits together.
This means that we have a total of 24+48 = 72 ways where either one or both couples sit together. How many total ways can we arrange 5 people? 5! = 120. 120 - 72 = 48 ways in which no couples sit together.
P(no couples together) = 48/120 = 2/5.